Stereochemical Assignment of Conjugated Carbonyls with a Prostaglandin-like Ring Structure Formed During Autoxidaion of Linolenate
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چکیده
منابع مشابه
Reaction of glutathione with conjugated carbonyls.
1. GSH reacts with conjugated carbonyls according to the equation: GSH+R-CH=CH-COR in equilibrium R-CH(SG)-CH2-COR. The forward reaction follows second order, the reverse reaction first order kinetics. It is assumed that this reaction reflects best the ability of conjugated carbonyls to inactivate SH groups in biological systems. 2. The rate of forward reaction increases with pH approx. paralle...
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ژورنال
عنوان ژورنال: Journal of Japan Oil Chemists' Society
سال: 2000
ISSN: 1341-8327,1884-1996
DOI: 10.5650/jos1996.49.831